赵雪,邱平达,姜海静,金振兴,蔡克迪

• 1:渤海大学辽宁省超级电容器工程技术研究中心
• 2:清华大学核能与新能源技术研究院

摘要(Abstract)：

超级电容器是介于传统电容器与化学电源之间的一种新型储能元件,它具有充电时间短、循环寿命长、功率特性好、温度范围宽和经济环保等优势,目前在很多领域都受到广泛关注。概述了超级电容器电极材料研究的最新进展,包括碳基材料、金属氧化物材料及导电聚合物材料等,并在此基础上对其未来发展趋势进行了展望。

关键词(KeyWords)： 超级电容器;电极材料;综述;研究进展;电极;复合材料

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金资助(No.21206083);; 辽宁省高校优秀人才支持计划第一层次资助项目(No.LR2014033)

作者(Author): 赵雪,邱平达,姜海静,金振兴,蔡克迪

DOI: 10.14106/j.cnki.1001-2028.2015.01.001

参考文献(References)：

• [1]何铁石,金振兴,张纯娇.超级电容器制备与应用[M].北京:原子能出版社,2011.
• [2]CAI K D,MU W F,HE T S,et al.Investigation of the electrode molding technologies for the carbon-based supercapacitors[J].J Solid State Electrochem,2012,16(7):2541-2546.
• [3]JIN Z X,MU W F,ZHANG C J,et al.Activated carbon modified by coupling agent for supercapacitor[J].Electrochim Acta,2012,59(1):100-104.
• [4]CAI K D,MU W F,ZHANG Q G,et al.Study on the application of N,N-1,4-Diethyl,triethylene,and diamine tetrafluoroborate in supercapacitors[J].Electrochem Solid State Lett,2010,13(11):A147-A149.
• [5]牧伟芳.超级电容器活性炭材料的表面改性及其电极性能研究[D].锦州:渤海大学,2009.
• [6]雷文,赵晓梅,何平,等.碳基超级电容器电极材料的研究进展[J].化学通报,2013,76(11):981-987.
• [7]JANG Y,JO J,CHOI Y M,et al.Activated carbon nanocomposite electrodes for high performance supercapacitors[J].Electrochim Acta,2013,102(15):240-245.
• [8]PENG C,YAN X B,WANG R T,et al.Promising activated carbons derived from waste tea-leaves and their application in high performance supercapacitors electrodes[J].Electrochim Acta,2013,87(1):401-408.
• [9]BHATTACHARJYA D,YU J S.Activated carbon made from cow dung as electrode material for electrochemical double layer capacitor[J].J Power Sources,2014,262(15):224-231.
• [10]HSU Y H,LAI C C,HO C L,et al.Preparation of interconnected carbon nanofibers as electrodes forsupercapacitors[J].Electrochim Acta,2014,127(1):369-376.
• [11]SUKEUN P,SEOK K.Effect of carbon blacks filler addition on electrochemical behaviors of Co3O4/graphene nanosheets as a supercapacitor electrodes[J].Electrochim Acta,2013(1):89516-522.
• [12]KIM K S,PARK S J.High electrochemical performance of carbon black-bonded carbonnanotubes for electrode materials[J].Mater Res Bull,2012,47(12):4146-4150.
• [13]WANG Y H,WANG C,CHENG W Y,et al.Dispersing WO3 in carbon aerogel makes an outstanding supercapacitor electrode material[J].Carbon,2014,69:287-293.
• [14]LEE Y J,PARK H W,HONG U G,et al.Mn-doped activated carbon aerogel as electrode material for pseudo-capacitive supercapacitor[J].Current Appl Phys,2012,12(4):1074-1080.
• [15]张海英.导电聚合物复合材料的合成及其在超级电容器电极材料中的应用研究[D].甘肃:西北师范大学,2012.
• [16]JESSE S,RICHARD L.Flexible supercapacitor yarns with coaxial carbon nanotube network electrodes[J].Materials Sci Engin:B,2014,184:34-43.
• [17]LEI C H,CONSTANTINA L.Activated carbon–carbon nanotube nanocomposite coatings for supercapacitor applications[J].Surface Coatings Technol,2013,232(15):326-330
• [18]HUANG K J,WANG L,ZHANG J Z,et al.One-step preparation of layeredmolybdenum disulfide/multi-walledcarbon nanotube composites for enhanced performance supercapacitor[J].Energy,2014,67(1):234-240.
• [19]SANKAPAL B R,GAJARE H B,DUBAL D P,et al.Presenting highest supercapacitance for Ti O2/MWNTs nanocomposites:novel method[J].Chem Engin J,2014,247(1):103-110.
• [20]ZHU Z J,HU Y J,JIANG H,et al.A three-dimensional ordered mesoporous carbon/carbon nanotubes nanocomposites for supercapacitors[J].J Power Sources,2014,246(15):402-408.
• [21]滕牧.石墨烯基材料在超级电容器中的应用[J].电子元件与材料,2014,33(9):11-13.
• [22]何铁石,赵龙,刘志成,等.石墨烯基超级电容器电极材料研究进展[J].电子元件与材料:2011,30(12):71-73.
• [23]FAN W,XIA Y Y,WENG W T,et al.Nitrogen-doped graphene hollow nanospheres as novel electrode materials for supercapacitor applications[J].J Power Sources,2013,243(1):973-981.
• [24]HUANG K J,WANG L,LIU Y J,et al.Layered Mo S2-graphene composites for supercapacitor applications with enhanced capacitive performance[J].Inter J Hydrogen Energy,2013,38(32):14027-14034.
• [25]JIANG Z J,JIANG Z Q,CHEN W H.The role of holes in improving the performance of nitrogen-doped holey graphene as an active electrode material for supercapacitorand oxygen reduction reaction[J].J Power Sources,2014,251(1):55-65.
• [26]SAMEH H,MASAAKI S,SHINSUKE M,et al.Mn O2/carbon nanowalls composite electrode for supercapacitorapplication[J].J Power Sources,2014,249(1):21-27.
• [27]BAHLOUL A,NESSARK B,BRIOT E,et al.Polypyrrole-covered Mn O2 as electrode material forsupercapacitor[J].J Power Sources,2013,240(15):267-272.
• [28]ZHAO Y,JIANG P.Mn O2 nanosheets grown on the Zn O-nanorodmodified carbon fibers for supercapacitor electrode materials[J].Colloids Surfaces A:Physicochem Engin Aspects,2014,444(5):232-239.
• [29]ZHANG Z Q,MA C C,HE L,et al.Facile synthesis of ATO/Mn O2 core–shell architectures for electrochemical capacitive energy storage[J].Ceram Inter,2014,40(7):10309-10315.
• [30]DENG J C,KANG L T,BAI G L,et al.Solution combustion synthesis of cobalt oxides(Co3O4 and Co3O4/Co O)nanoparticles as supercapacitor electrode materials[J].Electrochim Acta,2014,132(20):127-135.
• [31]TANG H W,GAO N,CHANG Z R,et al.Electrochemical performance of Na Co2O4 as electrode for supercapacitors[J].Chin Chem Lett,2014,25(2):269-272.
• [32]KUANG M,ZHANG W,GUO X L,et al.Template-free and large-scale synthesis of hierarchical dandelion-like Ni Co2O4 microspheres for high-performance supercapacitors[J].Ceram Intern,2014,40(7):10005-10011.
• [33]YANG Z H,XU F F,ZHANG W X,et al.Controllable preparation of multishelled Ni O hollow nanospheres via layer-by-layer self-assembly for supercapacitor application[J].J Power Sources,2014,246(15):24-31.
• [34]SUN Y J,XIAO X P,NI P J,et al.DNA-templated synthesis of nickel cobaltite oxide nanoflake for high-performance electrochemical capacitors[J].Electrochim Acta,2014,121(1):270-277.
• [35]YU W,JIANG X B,DING S J,et al.Preparation and electrochemical characteristics of porous hollow spheres of Ni O nanosheets as electrodes of supercapacitors[J].J Power Sources,2014,256(15):440-448.
• [36]ZHAO B,ZHUANG H,FANG T,et al.Self-assembly of Ni O/graphene with three-dimension hierarchical structure as high performance electrode material for supercapacitors[J].J Alloys Compd,2014,597(5):291-298.
• [37]刘剑洪,吴双泉,何传新,等.碳纳米管和碳微米管的结构、性质及其应用[J].深圳大学学报理工版,2013,30(1):291-298.
• [38]ZHANG F,XIAO F,DONG Z H,et al.Synthesis of polypyrrole wrapped graphene hydrogels composites as supercapacitor electrodes[J].Electrochim Acta,2013,114(30):125-132.
• [39]YUE B B,WANG C Y,DING X,et al.Electrochemically synthesized stretchable polypyrrole/fabricelectrodes for supercapacitor[J].Electrochim Acta,2013,113(15):17-22.
• [40]ZHANG H Q,HU L W,TU J G,et al.Electrochemically assembling of polythiophene film in ionic liquids(ILs)microemulsions and its application in an electrochemical capacitor[J].Electrochim Acta,2014,120(20):122-127.
• [41]CAO H L,ZHOU X F,ZHANG Y M,et al.Micros pherical polyaniline/graphene nanocomposites for high performance supercapacitors[J].J Power Sources,2013,243(1):715-720.
• [42]WANG X,LI H D,LIU P.Well-defined aniline-triphenylamine copolymer nanotubes:preparation,photoluminescent,and electrochemical properties[J].Electrochim Acta,2014,125(10):630-636.